A combined desalination–electrolysis system that can produce green hydrogen directly from seawater has been developed by a team in China. This integrated process uses a low-energy method to purify seawater, making it one of the first viable approaches to use salt water as a source of hydrogen. The purification step uses phase transitions to remove impurities and could have additional applications in wastewater treatment and resource recovery.
Splitting water with electricity has been experimented with for over 200 years and the reactions involved are well-understood: at the cathode, H+ ions gain electrons to form hydrogen gas whilst OH- loses electrons at the anode to form oxygen. But despite the simplicity of the underlying chemistry, effective electrolysis is a particularly complicated process. Water splitting is thermodynamically unfavourable and requires both specifically designed catalytic electrodes and a significant input of energy to drive the reaction. Even trace impurities can damage the delicate structure of the cell, leading to membrane pores becoming blocked, expensive electrodes corroded and unwanted byproducts formed.
Chloride ions in seawater are a particular problem and undergo competing oxidation at the anode to produce chlorine. Not only does this side reaction reduce the electrochemical efficiency of the cell, but chlorine is an extremely corrosive gas which rapidly degrades the electrodes and inactivates the cell. ‘Approaches to suppress corrosion by coating catalysts have had modest success,’ explains Heping Xie, an energy chemist at Shenzhen University in China. ‘But the composition of seawater changes [with] location, season [and] human behaviour so electrolysers can’t be universally compatible.’ With an average salt concentration of around 3.5%, the chloride content of seawater makes direct electrolysis unfeasible.
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